研究キーワード
Nanocars, molecular motors, Single molecules, Molecular machines
研究分野
ナノテク・材料 / 基礎物理化学 /
研究室概要
バイオミメティックスおよびテクノミメティクスに基づく分子マシンの設計 ・ 合成とナノ機械工学および生物応用に関する研究・教育を行う。
学術論文
"Synthesis and spectroscopic properties of diarylethene-subporphirinoid hybrids," ChemPhysChem, vol.25, 20 Sep. 2024
T. Muto, M. Yamada, N. Tamiya, A. Takagi, T. Mizutani, D. Bourissou, G. Rapenne, Tsuyoshi Kawai
[ doi:10.1002/cphc.202400615 ]
"Synthesis of Ce(IV) Heteroleptic Double-Decker Complex with a New Helical Naphthalocyanine as a Potential Gearing Subunit," Chem. Eur. J. , vol.30, 29 Jul. 2024
J. D. Subramanian, Hattori Yohei, F. Asanoma, T. Nishino, K. Yasuhara, C. J. Martin, Gwenael Rapenne
[ doi:10.1002/chem.202402470 ]
"Procrystalline self-assembly of desymmetrized pentaphenylcyclopentadiene," J. Phys. Chem. Lett. , vol.15, pp7628-7634, 20 Jul. 2024
D. Li, S. Seki, A. Ishikawa, K. Omoto, K. Yasuhara, G. Rapenne, S. Kawai
[ doi:10.1021/acs.jpclett.4c01364 ]
"Copper-catalyzed perarylation of cyclopentadiene: Synthesis of hexaarylcyclopentadienes," Chem. Sci. , vol.15, pp9127-9137, 16 May. 2024
Y. Gisbert, P. Simón-Marqués, C. Baccini, S. Abid, N. Saffon-Merceron, G. Rapenne, C. Kammerer
[ doi:10.1039/D4SC02458C I ]
"Lipid nanodiscs spontaneously formed by an amphiphilic polymethacrylate derivative as an efficient nanocarrier for molecular delivery to intact cells ," RSC Advances , vol.14, pp6127-6134, 19 Feb. 2024
J. Hao, G. Rapenne, K. Yasuhara
[ doi:10.1039/D3RA07481A ]
"Synthesis and dynamic behavior of Ce(IV) double-decker complexes of sterically-hindered phthalocyanines," Molecules , vol.29, pp888, 17 Feb. 2024
J. D. Subramanian, T. Nishino, K. Yasuhara, G. Rapenne
[ doi:10.3390/molecules29040888 ]
"Synthesis of p-conjugated polycyclic compounds by late-stage extrusion of chalcogen fragments," J. Org. Chem. , vol.20, pp287-305, 15 Feb. 2024
A. Okba, P. Simon-Marques, K. Matsuo, N. Aratani, H. Yamada, G. Rapenne, C. Kammerer, Beilstein
[ doi:10.3762/bjoc.20.30 ]
"Lipid cubic phase with an organic-inorganic hybrid structure formed by organoalkoxysilane lipid," Chem. Commun. , vol.60, pp2168-2171, 11 Jan. 2024
M. Kariya, K. Omoto, K. Nomura, K. Yonezawa, H. Kamikubo, T. Nishino, T. Inoie, G. Rapenne, K. Yasuhara
[ doi:10.1039/D3CC05167F ]
"Synthesis of symmetric and dissymmetric star-shaped pentaarylcyclopentadienyl Ru(II) complexes containing styryl-BODIPY fragments," Chem. Lett. , vol.53, 1 Dec. 2023
M. Dumartin, S. Abid, Y. Gisbert, N. Saffon-Merceron, S. Gao, N. Armaroli, B. Ventura, C. Kammerer, Gwenael Rapenne
[ doi:10.1093/chemle/upad003 ]
" Multiply engaged molecular gear composed of Ce(IV) double-decker of a triptycene-functionalized porphyrin," Dalton Trans., vol.52, pp11797-11801, 9 Aug. 2023
T. Nishino, M. Fukumura, K. Yasuhara, S. Katao, G. Rapenne
[ doi:10.1039/D3DT02443A ]
"Multiply Engaged Molecular Gear composed of Cerium (IV) Double-Decker of a triptycene-functionalized Porphyrin," Dalton Transactions, vol.52, pp11797-11801, 9 Aug. 2023
T. Nishino, M. Fukumura, S. Katao, K, Kazuma Yasuhara, G. Rapenne
[ doi:10.1039/D3DT02443A ]
"Investigations into oxidation induced ring opening of terarylenes containing π-extended thieno [b] thiophene units.," New J. Chem. , vol.47, pp2832-2839, Jun. 2023
C. J. Martin, Y. Goto, R. Asato, Gwenael Rapenne, Tsuyoshi Kawai
[ doi:10.1039/D2NJ05726C ]
" Extended tripodal hydrotris(indazol-1-yl)borate ligands as ruthenium-supported cogwheels for on-surface gearing motions," Chem. Eur. J., vol.29, 25 Jan. 2023
K. Omoto, M. Shi, K. Yasuhara, C. Kammerer, G. Rapenne
[ doi:10.1002/chem.202203483 ]
"Extended Tripodal Hydrotris(indazol-1-yl)borate Ligands as Ruthenium-Supported Cogwheels for On-Surface Gearing Motions," Chemistry - A European Journal, vol.29, ppe202203483, 25 Jan. 2023
K. Omoto, M. Shi, K. Yasuhara, Claire Kammerer, Gwenael Rapenne
[ doi:10.1002/chem.202203483 ]
"Investigations into terarylenes containing π-extended thieno[b]thiophene units," New J. Chem., vol.47, pp2832-2839, 27 Dec. 2022
C.J. Martin, Y. Goto, R Asato, Gwenael Rapenne, Tsuyoshi Kawai
[ doi:10.1039/D2NJ05726C ]
"Thermally responsive morphological changes of layered coordination polymers induced by disordering/ordering of flexible alkyl chains," Dalton Trans., vol.51, pp17967-17972, 1 Nov. 2022
K. Omoto, S. Aoyama, T. Galica, E. Nishibori, S. Kato, K. Yasuhara, G. Rapenne
[ doi:10.1039/D2DT03142F ]
"第2回国際ナノカーレース参戦記 -ナノメートルスケールのル・マン24時間耐久レース," 化学, vol.77, pp44-48, 2022.7.20
西野 智雄, 安原 主馬, Gwénaël Rapenne
"Designed amphiphiles for cell membrane mimetic nanoarchitecture," in Nanoscience & Nanotechnology Series No. 55. Concepts and Design of Materials Nanoarchitectonics, pp361-380, 16 Feb. 2022
K. Yasuhara, K. Omoto, T. Nishino, G. Rapenne
[ doi:10.1039/9781788019613 ]
"Energy Storage upon Photochromic 6-pi Photocyclization and Efficient On-Demand Heat Release with Oxidation Stimuli," JOURNAL OF PHYSICAL CHEMISTRY LETTERS, vol.12, pp11391-11398, 25 Nov. 2021
Asato Ryosuke, Martin Colin J., Nakashima Takuya, Calupitan Jan Patrick, Gwenael Rapenne, Tsuyoshi Kawai
[ doi:10.1021/acs.jpclett.1c03052 ]
"Molecular vehicles based on a polyaromatic or porphyrinic chassis," J. Synth. Org. Chem. Jpn , vol.79, pp1050-1055, 1 Nov. 2021
T. Nishino, C.J. Martin, K. Yasuhara, G. Rapenne
[ doi:10.5059/yukigoseikyokaishi.79.1050 ]
"Divergent synthesis of molecular winch prototypes," Chem. Eur. J. , vol.27, pp16242-16249, 13 Oct. 2021
Y. Gisbert, C. Kammerer, G. Rapenne
[ doi:10.1002/chem.202103126 ]
" Photophysical properties of 1,2,3,4,5-pentaphenylcyclopentadienyl hydrotris(indazolyl) borate ruthenium(II) complexes," Phys. Chem. Chem. Phys., vol.23, pp17049-17056, 15 Jul. 2021
S. Gao, Y. Gisbert, G. Erbland, S. Abid, C. Kammerer, A. Venturini, G. Rapenne, * B. Ventura, * N. Armaroli
[ doi:10.1039/D1CP02261J ]
"Molecular gears from solution to surfaces," Chem. Eur. J., vol.27, pp12019-12031, 16 Jun. 2021
Y. Gisbert, S. Abid, C. Kammerer, G. Rapenne
[ doi:10.1002/chem.202101489 ]
"Ruthenium complexes of sterically-hindered pentaphenylcyclopenta dienyl ligands ," RSC Advances, vol.11, pp20207-20215, 7 Jun. 2021
R Asato, C.J. Martin, Y. Gisbert, S. Abid, T. Kawai, C. Kammerer, G. Rapenne
[ doi:10.1039/D1RA03875C ]
"A molecular rotor functionalized with a photoresponsive brake," Inorg. Chem. , vol.60, pp3492-3501, 19 Feb. 2021
R. Asato, C. J. Martin, S. Abid, Y. Gisbert, F. Asanoma, T. Nakashima, C. Kammerer, T. Kawai, G. Rapenne
[ doi:10.1021/acs.inorgchem.0c03330 ]
"Desymmetrised pentaporphyrinic gears mounted on metallo-organic anchors," Chem. Sci. , vol.2021,12, pp4709-4721, 18 Feb. 2021
S. Abid, Y. Gisbert, M. Kojima, N. Saffon-Merceron, J. Cuny, C. Kammerer, G. Rapenne
[ doi:10.1039/D0SC06379G ]
"単一分子マシンの化学 機械のような分子一つを見る・動かす," 現代化学,, vol.2020,596, pp42-45, 2020.11.1
西野智雄, Gwénaël Rapenne
"Mechanics of molecule-gears with six long teeth," J. Phys. Chem. , vol.C2020,124, pp22625-22630, 5 Oct. 2020
W.-H. Soe, M. Kleinwachter, C. Kammerer, G. Rapenne, C. Joachim
[ doi:10.1021/acs.jpcc.0c08194 ]
"Transmitting Stepwise Rotation among Three Molecule-Gear on the Au(111) Surface," J. Phys. Chem. Lett., vol.11, pp6892-6899, 2020.8.11
K.H.A. Yeung, T. Künhe, F. Eisenhut, M. Kleinwachter, Y. Gisbert, R. Robles, N. Lorente, G. Cuniberti, C. Joachim, G. Rapenne, C. Kammerer, F. Moresco
[ doi:10.1021/acs.jpclett.0c01747 ]
"Systematic studies of structural variations in terarylene photohydride generators," J. Photochem Photobiol. A, vol.397, pp112594, 15 Jun. 2020
C.J. Martin, J.P. Calupitan, M. Minamide, R. Asato, Y. Goto, G. Rapenne, T. Nakashima, Tsuyoshi Kawai
[ doi:10.1016/j.jphotochem.2020.112594 ]
"Dipolar Nanocars Based on a Porphyrin Backbone," Chemistry - A European Journal, vol.26, pp12010-12018, 12 Jun. 2020
Toshio Nishino, Colin J. Martin, Hiroki Takeuchi, Florence Lim, Kazuma Yasuhara, Yohan Gisbert, Seifallah Abid, Nathalie Saffon-Merceron, Claire Kammerer, Gwenael Rapenne
[ doi:10.1002/chem.202001999 ]
"Dipolar nanocars based on a porphyrin backbone," Chem. Eur. J. , vol.26, pp12010-12018, 12 Jun. 2020
T. Nishino, C. J. Martin, H. Takeuchi, F. Lim, K. Yasuhara, Y. Gisbert, S. Abid, N. Saffon‐Merceron, C. Kammerer, G. Rapenne
[ doi:10.1002/chem.202001999 ]
"Modular synthesis of pentaarylcyclopentadienyl Ru-based molecular machines via sequential Pd-catalysed cross coupling," Chem. Commun, vol.55, pp14689-14692, Nov. 2019
Y. Gisbert, S. Abid, G. Bertrand, Nathalie Saffon-Merceron, C. Kammerer, G. Rapenne
[ doi:10.1039/C9CC08384G ]
"Star-shaped ruthenium complexes as prototypes of molecular gears," Chem. Eur. J. , vol.25, pp16328-16339, 11 Oct. 2019
G. Erbland, S Abid, Y. Gisbert, Nathalie Saffon-Merceron, Yusuke Hashimoto, L. Andreoni, T. Guérin, C. Kammerer, G. Rapenne
[ doi:10.1002/chem.201903615 ]
"A chiral molecular propeller designed for unidirectional rotations on a surface," Nature Commun, vol.10, pp3742-1-3742-9, Aug. 2019
Y. Zhang, J.P. Calupitan, T. Rojas, R. Tumbleson, G. Erbland, C. Kammerer, T.M. Ajayi, S. Wang, L.C. Curtiss, A.T. Ngo, S.E. Ulloa, G. Rapenne, S.W. Hla
[ doi:10.1038/s41467-019-11737-1 ]
"Photochromic Diarylethenes Designed for Surface Deposition: From Self-Assembled Monolayers to Single Molecules," CHEMPLUSCHEM, vol.84, pp564-577, Jun. 2019
Jan Patrick Dela Cruz Calupitan, Olivier Galangau, Takuya Nakashima, Tsuyoshi Kawai, Gwenael Rapenne
[ doi:10.1002/cplu.201800640 ]
"Biomimetic and technomimetic single molecular machines," Chem. Lett. 2019, 48, 299-308. , vol.48, pp299-308, 5 Apr. 2019
C. Kammerer, G. Erbland, Y. Gisbert, T. Nishino, K. Yasuhara, G. Rapenne
"Photochromic diarylethenes designed for surface deposition: from self-assembled monolayers to single molecules," ChemPlusChem. , vol.84, pp564-577, 7 Feb. 2019
J. P. Calupitan, O. Galangau, T. Nakashima, T. Kawai, G. Rapenne
[ doi:10.1002/cplu.201800640 ]
"Biomimetic and Technomimetic Single Molecular Machines ," Chem. Lett., vol.48, pp299-308, 23 Jan. 2019
C. Kammerer, G. Erbland, Y. Gisbert, T. Nishino, K. Yasuhara, G. Rapenne
[ doi:10.1246/cl.181019 ]
"Biomimetic and technomimetic single molecular machines," Chem. Lett., vol.48, pp299-308, Jan. 2019
C. Kammerer, G. Erbland, Y. Gisbert, T. Nishino, K. Yasuhara, G. Rapenne
[ doi:10.1246/cl.181019 ]
"Terarylenes as Photoactivatable Hydride Donors," JOURNAL OF ORGANIC CHEMISTRY, vol.83, pp13700-13706, 16 Nov. 2018
Martin, Colin J., Minamide, Miho, Calupitan, Jan Patrick Dela Cruz, Asato, Ryosuke, Kuno, Jumpei, Takuya Nakashima, Gwenael Rapenne, Tsuyoshi Kawai
[ doi:10.1021/acs.joc.8b01877 ]
"Surface manipulation of a corved polycyclic aromatic hydrocarbon-based nanovehicle equipped with triptycene wheels," Nanotechnology, pp29-495401, 1 Oct. 2018
W.-H. Soe, C. Durand, S. Gauthier, H.-P. Jacquot de Rouville, C. Kammerer, G. Rapenne, C. Joachim
"Terarylene as Possible Photoactivatable Hydride Donor," J. Org. Chem, pp13700-13706, 1 Oct. 2018
C. Martin, M. Minamide, J.P.D.C. Calupitan, J. Kuno, T. Nakashima, G. Rapenne, T. Kawai
"Hierarchical emergence and dynamic control of chirality in a photoresponsive dinuclear complex," pp2151-2157, 12 Sep. 2018
Y.Hashimoto, T.Nakashima, M.Yamada, J.Yuasa, T.Kawai, J.Phys, G.Rapenne
"From the Synthesis of a Molecular Wheel to the First Nanocar Race," pp317-320, 12 Sep. 2018
G.Rapenne, K.Yasuhara
"Expedient Synthesis of thioeter -functionnalized hydrotris(indazolyl)borate as an anchoring platform for rotary molecular machines," pp4731-4739, 2018.9.12
G.Erabland, Y.Gisbert, G.Rapenne
"Expedient synthesis of thioether-functionalized hydrotris(indazolyl) borate as an anchoring platform for rotary molecular machines," Eur. J. Org. Chem., pp4731-4739, 1 Sep. 2018
G. Erbland, Y. Gisbert, G. Rapenne, C. Kammerer
"Hierarchical Emergence and Dynamic Control of Chirality in a Photoresponsive Dinuclear Complex," J. Phys. Chem. Lett., vol.9, pp2151-2157, Apr. 2018
Y. Hashimoto, T. Nakashima, M. Yamada, J. Yuasa, G. Rapenne, T. Kawai
[ doi:10.1021/acs.jpclett.8b00690 ]
"Adsorption of Terarylenes on Ag(111) and NaCl(001)/Ag(111): A Scanning Tunneling Microscopy and Density Functional Theory Study," vol.122, pp5978-5991, 22 Mar. 2018
Jan Patrick Dela Cruz Calupitan, Olivier Guillermet, Olivier Galangau, Mayssa Yengui, Jorge Echeverria, Xavier Bouju, Takuya Nakashima, Gwenael Rapenne, Roland Coratger, Tsuyoshi Kawai
[ doi:10.1021/acs.jpcc.7b11122 ]
" From the synthesis of nanovehicles to the participation at the first Nanocar Race ," Molecules, pp612-623, 1 Mar. 2018
H.-P. Jacquot de Rouville, C. Kammerer, G. Rapenne
"Recent progress in development of photoacid generators," JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, vol.34, pp41-51, Mar. 2018
Colin J. Martin, Gwenael Rapenne, Takuya Nakashima, Tsuyoshi Kawai
[ doi:10.1016/j.jphotochemrev.2018.01.003 ]
"Adsorption of Terarylenes on Ag(111) and NaCl(001)/Ag(111): a Scanning Tunneling Microscopy and Density Functional Theory Study," J. Phys. Chem. C, vol.122, pp5978-5991, Feb. 2018
J. P. D. C. Calupitan, O. Guillermet, O. Galangau, M. Yengui, J. Echeverria, X. Bouju, T. Nakashima, G. Rapenne, R. Coratger, T. Kawai
[ doi:10.1021/acs.jpcc.7b11122 ]
"Recent Progress in Development of Photoacid Generators," J. Photochem. Photobiol. C, vol.34, pp41-51, Jan. 2018
C. Martin, G. Rapenne, T. Nakashima, T. Kawai
[ doi:10.1016/j.jphotochemrev.2018.01.003 ]
受賞
"膜シンポジウム 2019 学生賞," Nov. 2019
Hao Jinyu, Yuma Mitsuyoshi, Gwenael Rapenne, Kazuma Yasuhara
所属学協会
資料

安原 主馬

職位 准教授
領域 物質創成科学領域 基幹研究室
研究室 バイオ・テクノミメティック分子科学

バイオミメティックスおよびテクノミメティクスに基づく分子マシンの設計 ・ 合成とナノ機械工学および生物応用に関する研究・教育を行う。

西野 智雄

職位 助教
領域 物質創成科学領域 基幹研究室
研究室 バイオ・テクノミメティック分子科学

バイオミメティックスおよびテクノミメティクスに基づく分子マシンの設計 ・ 合成とナノ機械工学および生物応用に関する研究・教育を行う。

服部 陽平

職位 特任助教
領域 物質創成科学領域 基幹研究室
研究室 バイオ・テクノミメティック分子科学

バイオミメティックスおよびテクノミメティクスに基づく分子マシンの設計 ・ 合成とナノ機械工学および生物応用に関する研究・教育を行う。